About Principle of chemical decomposition of photovoltaic panels
In this comprehensive work, we have summarized (i) the classification of photovoltaic technology, (ii) review the approaches embraced for photovoltaic (PV) waste management on a global level, (iii) the need for photovoltaic (PV) waste management and brief explanation on the recycling process (Mechanical, thermal, chemical and leaser methods) of .
In this comprehensive work, we have summarized (i) the classification of photovoltaic technology, (ii) review the approaches embraced for photovoltaic (PV) waste management on a global level, (iii) the need for photovoltaic (PV) waste management and brief explanation on the recycling process (Mechanical, thermal, chemical and leaser methods) of .
In this work two different routes for the treatment of photovoltaic modules were considered: a chemical process and a physical process. The chemical process consisted of dissolution with organic solvents of ethylene vinyl acetate (EVA) which holds the materials to recover, namely glass, metals, and the support, which was a film of polyvinyl .
In this framework, some issues concerning the end of life photovoltaic panels must be taken into account to definitively assess the environmental impact of PV technology, including the consumption of energy and reagents, and the emissions of pollutants that can be generated by the recycling and recovery processes (Tammaro et al., 2015).
The conditions of thermal and chemical treatment were optimized to separate metals and recover silicon from damaged PV panels. The thermal method was applied to remove EVA. The explored factors for this step were time interval and temperature that would ensure minimum energy expenditure and complete combustion of samples.
Radziemska et al. used a thermal process to decompose the EVA, followed by a chemical treatment for the solar cell, which they refer to as a second primary step in PV modules’ recycling. Kang et al. [ 20 ] employed a mixture of acid solvents in the process of etching Si solar panels.
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